kg/kkg (16/1,000 lb) pounds of pollutant per 1000 lbs product Pesticide Notes Daily maximum shall not exceed Monthly average Propachlor 3.74 x 10-> 1.11 x 10-1 Propanil 7.63 x 10 3.48 x 10 Propazine 5.56 x 10 1.82 x 10 Pyrethrin I and Pyrethrin !! 8.91 x 10 2.40 x 10 Simazine 5.89 x 10-3 1.91 x 10-3 Stirotos 2.95 x 10-3 9.72 x 10-4 TCMTB 2.80 x 10-9 7.54 x 10-4 Tebuthiuron 9.78 x 10-2 3.41 x 10-2 Terbacil 2.76 x 10-1 8.36 x 10-2 Terbufos 4.92 x 10-4 1.26 x 10-4 Terbuthylazine 5.56 x 10-3 1.82 x 10-3 Terbutryn 5.56 x 10 1.82 x 10-3 Toxaphene 7.35 x 10-3 2.67 x 10-3 Triadimeton 4.69 x 10-2 2.46 x 10-2 Trifluralin 3.22 x 10 1.09 x 10-4 Vapam (Sodium methyldithiocarbamate) 4.14 x 10-3 1.35 x 10-3 Ziram (Zinc dimethyldithiocarbanate) 4.14 x 10-3 1.35 x 10-3 4 Applies to purification by recrystalization portion of the process. 1 Daily maximum shall not exceed Monthly average shall not exceed 16 21 68 22 22 25 25 54 211 230 163 54 44 28 98 112 36 136 380 380 1.1-Dichloroethylene 1.1.1-Trichloroethane 1,2-Dichloroethane 1,2-Dichloropropane 12-Dichlorobenzene 1.2-trans-Dichloroethylene 1,3-Dichloropropene 1,4-Dichlorobenzene 2-chlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol Benzene Bromodichloromethane Bromomethane Chlorobenzene Chloromethane Cyanide (Total) Dibrorochloromethane Dichloromethane Ethylbenzene Lead (Total) Naphthalene Phenol Tetrachloroethylene Tetrachloromethane Toluene Tribromomethane Trichloromethane 28 1,1-Dichloroethylene 153 77 21 29 15 31 39 18 37 142 142 15 86 220 196 40 32 320 22 15 22 18 26 196 21 60 59 66 794 794 574 794 380 47 134 380 380 380 295 640 794 170 380 690 47 47 164 380 196 180 196 142 19 57 142 142 142 110 220 196 74 794 325 190 640 794 89 108 690 59 26 56 38 80 794 46 36 142 320 19 19 52 142 28 196 111 507/ TABLE 7 TO PART 455–TEST METHODS FOR PESTICIDE ACTIVE INGREDIENTS EPA survey Pesticide name CAS No. code EPA analytical method No.(s) 8 12 16 43121-43-3 00062-73–7 00094-75-7 17 00094-82-6 22 25 26 27 07786-34-7 21725–46-2 01918-16-7 00094-74-6 30 00120-36-5 31 Triadimeton and Esters (2,4Dichlorophenoxyacetic acid). 2,4-DB; 2,4-DB Salts and Esters (2,4. Dichlorophenoxybutyric acid). Mevinphos Cyanazine Propachlor MCPA; MCPA Salts and Esters (2-Methyl-4 chlorophenoxyacetic acid). Dichlorprop: Dichlorprop Salts and Esters (2-(2,4 Dichlorophenoxy) propionic acid). MCPP; MCPP Salts and Esters (2-(2-Methyl-4 633/525.1/1656 1657/507/622/525.1 1658/515.1/615/515.2555 1658/515.1/ 615/515.2/555 1657/507/622/525. 629 507 1656/508/608.1/525.1 1658/615/555 1658/515.1/615/515.2/555 00093-65-2 1658/615/555 35 39 41 45 52 53 54 55 58 60 62 68 69 69 70 73 75 76 80 82 84 86 90 103 107 110 112 113 118 119 123 chlorophenoxy) propionic acid). 21564-17-0 637 525, 1/507/633.1 632.1/1656 507/633/525.1/1656 1656/1657 515.1/515 2/555 505/507/645/525.1/1656 531.1 507/619/525.1 505/507/619/525.1/1656 631 507/633/525.1/1656 1625/1661 1656 507/645/525.1/1656 1656 531.1/632553 531.1/632 1656/508/608.1/525.1 508/608.2/525.1/1656 1657/507/622/5251 1657/508/622 1660 1657/507/614/622/525.1 1657/614622 508/608.2/525. 1/515.1/515.2/1656 1658/515.1/615/515.2/555 1657/614.1 630.1 632/553 548/548.1 EPA survey code Pesticide name CAS No. EPA analytical method No.(s) 124 Endrin 125 Ethalfluralin 126 Ethion 127 Ethoprop 132 Fenarimol 133 Fenthion 138 Glyphosate (N-(Phosphonomethyl) glycine) 140 Heptachlor Isopropalin 148 Linuron 150 Malathion 154 Methamidophos 156 Methomyi 158 Methoxychlor 172 Nabam 173 Naled 175 Norflurazon 178 Benfluralin 182 Fensulfothion 183 Disulfoton 185 Phosmet 186 Azinphos Methyl 192 Organo-tin pesticides 197 Bolstar 203 Parathion 204 Pendimethalin 205 Pentachloronitrobenzene 206 Pentachlorophenol 208 Permethrin 212 Phorate 218 Busan 85 (Potassium dimethyldithiocarbamate) 219 Busan 40 (Potassium N-hydroxymethyl-N methyldithiocarbamate). 220 KN Methyl (Potassium N-methyldithiocarbamate) 223 Prometon 224 Prometryn 226 Propazine 230 Pyrethrin 1 232 Pyrethrin 11 DEF (S.S, S-Tributyl phosphorotrithioate) 239 Simazine 241 Carbam-S (Sodium dimethyldithiocarbanate) 243 Vapam (Sodium methyldithiocarbamate) 252 Tebuthiuron 254 Terbacil 255 Terbutos 256 Terbuthylazine 257 Terbutryn 259 Dazomet 262 Toxaphene 263 Merphos (Tributyl phosphorotrithioate) 264 Trifluralin 268 Ziram (Zinc dimethyldithiocarbamate) Monitor and report as total Trifluralin. 00072-20-8 55283-68-6 00563-12-2 13194-48-4 60168-88-9 00055-38-9 01071-83-6 00076-44-8 33820-53-0 00330-55-2 00121-75-5 10265-92-6 16752-77-5 00072-43-5 00142-59-6 00300–76-5 27314-13-2 01861-40-1 00115-90-2 00298-04-4 00732-11-6 00086-50-0 12379-54-3 35400-43-2 00056-38-2 40487-42-1 00082-68-8 00087-86-5 52645-53-1 00298-02-2 00128-03-0 51026-28-9 1656/505/508/608/617/525.1 11656/ 627 1657/614/614.1 1657/507/622/525. 1 507/633.1/525.1/1656 1657/622 547 1656/505/508/608/617/525.1 1656/627 553/632 1657/614 1657 531.1/632 1656/505/508/608.2/617/525.1 630/630.1 1657/622 507/645/525.1/1656 11656/ 627 1657/622 1657/507/614/622/525.1 1657/622.1 1657/614/622 Ind-01/200.7/200.9 1657/622 1657/614 1656 1656/608.1/617 625/1625/515.2/555/515.1/ 525.1 608.2/508/525.1/1656/1660 1657/622 630/630.1 630/630.1 (58 FR 50699, Sept. 28, 1993) TABLE 8 TO PART 455—LIST OF POLLU TION PREVENTION ALTERNATIVE A modification to the list of practices on this table that an individual facility must comply with to be eligible for the pollution prevention alternative is allowed with acceptable justification as listed on this table as approved by the permit writer or control authority (using BPJ/BEJ) after submittal by the facility of a request for modification. A modification, for purposes of this table, means that a facility would no longer have to perform a listed practice or would need to comply with a modified practice. However, the modification only applies to the specific practice for which the modification has been justified and to no other listed practices. Facilities are required to thoroughly discuss all modifications in the on-site compliance paperwork as described above in the limitations and standards ($ 455.41(c)). 1. Must use water conservation practices. These practices may include, but are not limited to using: spray nozzles or flow reduction devices on hoses, low volume/high pressure rinsing equipment, floor scrubbing machines, mop(s) and bucket(s), and counter current staged drum rinsing stations. [Modification allowed when: Rinsing narrow transfer lines or piping where sufficient rinsing is better achieved by flushing with water.] 2. Must practice good housekeeping: (a) Perform preventative maintenance on all valves and fittings and repair leaky valves and fittings in a timely manner; (b) Use drip pans under any valves or fittings where hoses or lines are routinely connected and disconnected, collect for reuse when possible; and (c) Perform quick cleanup of leaks and spills in outdoor bulk storage or process areas. 3. Must sweep or vacuum dry production areas prior to rinsing with water. 4. Must clean interiors of dry formulation equipment with dry carrier prior to any water rinse. The carrier material must be stored and reused in future formulation of the same or compatible product or properly disposed of as solid waste. 5. If operating continuous overflow Department of Transportation (DOT) aerosol leak test baths-> Must operate with some recirculation. 6. If operating air pollution control wet scrubbers-> Must operate as recirculating scrubbers (periodic blowdown is allowed as needed). [Modification allowed when: Facility demonstrates that they would not be able to meet Resource Conservation Recovery Act or Clean Air Act (CAA) requirements.] 7. When performing rinsing of raw material drums, storage drums, and/or shipping containers that contained liquid PAI(s) and/or inert ingredients for the formulation of water-based products-> Must reuse the drum/shipping container rinsate DIRECTLY into the formulation at the time of formulation; or store for use in future formulation of same or compatible product; or use a staged drum rinsing station (counter current rinsing). [Modification allowed when: the drum/shipping container holds inert ingredient(s) only and (1) the facility can demonstrate that, after using water conservation practices, the large concentration of inert ingredient in the formulation creates more volume than could feasibly be reused; or (2) the facility can demonstrate that the concentration of the inert in the formulation is so small that the reuse would cause a formulation to exceed the ranges allowed in the Confidential Statement of Formula (CSF) (40 CFR 158.155).) 8. When performing rinsing of raw material drums, storage drums, and/or shipping containers that contained liquid PAI(s) and/or inert ingredients for the formulation of solvent-based products-> Must reuse the drum/shipping container rinsate DIRECTLY into the formulation at the time of formulation or store for use in future formulation of same or compatible product. [Modification allowed when: (a) The drum/shipping container holds inert ingredient(s) only and: (1) The facility can demonstrate that, after using water conservation practices, the large concentration of inert ingredient in the formulation creates more volume than could feasibly be reused; or (2) the facility can demonstrate that the concentration of the inert in the formulation is so small that the reuse would cause a formulation to exceed the ranges allowed in the Confidential Statement of Formula (CSF) (40 CFR 158.155); or (b) Drums/shipping containers are going to a drum refurbisher recycler who will only accept drums rinsed with water.) 9. Must dedicate PFPR production equipment by water-based versus solvent-based products. Dedicated solvent-based or waterbased equipment may be used on a non-routine basis for non-dedicated operations; however the facility may not discharge the solvent/aqueous changeover rinsate as part of their P2 allowable discharge (i.e., the facility must achieve zero discharge of those process wastewater pollutants). [Modification allowed when: Facility has installed and is using a solvent recovery system for the changeover rinsate (can also be used for other solvent recovery).) 10. Must store the rinsate from interior rinsing (does not include drum/shipping container rinsate) for reuse in future formulation of same or compatible product. [Modification allowed when: (a) Facility has evidence of biological growth or other product deterioration over a typical storage period; (b) Facility has space limitations, BUT must still store rinsates for most frequently produced products; (C) Manufacturer (or formulator tracting for toll formulating) has directed otherwise (i.e., send back to them or send for off-site disposal); (d) Facility is dropping registration or production of the formulation and there is no compatible formulation for reuse of the rinsates or facility can provide reasonable explanation of why it does not anticipate formulation of same or compatible formulation within the next 12 months; con (e) Facility only performs packaging of the pesticide product from which interior rinsate is generated; or (1) Facility has demonstrated that it must use a detergent to clean the equipment.] NOTES For indirect dischargers: After following the practices above, some wastewaters may require pretreatment prior to discharge to POTWs. See definition of pollution prevention allowable discharge for indirect dischargers ($ 455.41(d)). For direct dischargers: After following the practices above, all wastewaters require treatment prior to discharge directly to the nation's waters. See definition of pollution prevention allowable discharge for direct dischargers ($ 455.41(e)). Additional information and guidance on implementing these P2 practices as well as evaluating compliance with these practices will be available in a P2 Guidance Manual for the PFPR Industry. (61 FR 57553, Nov. 6, 1996] 079034 Methyl esters of fatty acids (100% C8 C12) 079059 Fatty alcohols (54.5% C10, 45.1% C8, 0.4% C6) 086803 Xylene range aromatic solvent 107302 Polyhedral inclusion bodies of Douglas fir tussock moth nucl. 107303 Polyhedral inclusion bodies of gypsy moth nucleopolyhedrosis. 107304 Polyhedral inclusion bodies of n sertifer 116902 Gibberellin A4 mixt. with Gibberellin A7. 117001 Nosema locustae. 128888 Lactofen (ANSI). 1289342 Nitrogen, liquid. 129029 Bergamot Oil. 224600 Diethanolamides of the fatty acids of co conut oil (coded 079). 505200 Isoparaffinic hydrocarbons. Shaughnessey codes and chemical names are taken directly from the FATES database. Several chemical names are truncated because the chemical names listed in the FATES database are limited to 60 characters. 2 EPA does not believe this PAI will persist in sanitary streams long enough to reach a POTW. (61 FR 57554, Nov. 6, 1996) TABLE 9 TO PART 455—GROUP 2 MIXTURES Shaughnessey code TABLE 10 TO PART 455_LIST OF APPRO PRIATE POLLUTION CONTROL TECH- Chemical name 1 002201 006501 006602 0166012 022003 025001 025003 025004 031801 055601 063501 063502 063503 063506 067003 067205 067207 067302 Sabadilla alkaloids. This table contains those pollutant control Aromatic petroleum derivative solvent. technologies, such as hydrolysis, chemical Heavy aromatic naphtha. Dry ice. oxidation, precipitation and activated carCoal tar. bon adsorption, which have been used for esCoal tar neutral oils. timating compliance costs on a PAI specific Creosote oil (Note: Derived from any basis. In general, these treatment techsource) nologies have been determined to be effecCoal tar creosote, tive in Ammonium salts of C8-18 and C18' fatty treating pesticide containing acids. wastewaters in literature, in bench or pilot BNOA. scale treatability studies or in the Pesticide Kerosene. Manufacturing effluent guidelines. These are Mineral oil-includes paraffin oil from the same technologies that are presented as 063503 part of the Universal Treatment System. Petroleum distillate, oils, solvent, or hydrocarbons, also p. However, these technologies are PAI specific Mineral spirits and may need to be used in conjunction with Terpineols (unspec.). one another to provide treatment for all Pine tar oil. PAIs used at a facility over a period of time. In addition, facilities may experience difAmines. N-coco alkyltrimethylenedi-, ace ficulties treating wastewaters that contain tates. Amines, coco alkyl, hydrochlorides. emulsions, therefore, “appropriate" treatRed Squill glycoside. ment for emulsified wastewaters must inCube Resins other than rotenone. clude an emulsion breaking step. For PAIS Ryania speciosa, powdered stems of. whose technology is listed as “Pollution PreSilica gel. vention", the permitting authority control Silicon dioxide. authority can determine if additional treatTurkey red oil. Potassium salts of fatty acids. ment is necessary through best professional Fatty alcohols (52-61% C10, 39–46% judgement/best engineering judgement, reC8, 0-3% C6, 0-3% C12). spectively. Ester gum. 069152 070801 071004 071501 0726022 0726052 079014 079021 079029 |
